Some users will have issues creating ipv6 subnets in Synology DSM.
To do so, use the command line
docker network create --ipv6 --subnet 2001:db8:85a3::8a2e:370:9100/120 --gateway 2001:db8:85a3::8a2e:370:9101 --ip-range 2001:db8:85a3::8a2e:370:9100/24 --subnet 192.168.225.0/24 --ip-range 192.168.225.0/24 --gateway 192.168.225.1 container
So:
Make sure you have enabled IPV6 on your SYnology primary network adapter and that it has received an address from your IPV6 router (i.e. your router). Once done, make sure on your router you add a static route for the subnet to the Synology interface (not the Docker interface).